HYDROGENATION OF CO OVER A COBALT/CERIUM OXIDE CATALYST FOR PRODUCTION OF LOWER OLEFINS
Advancing the chemical engineering fundamentals
Catalysis (T2-13P)
Keywords: Fischer Tropsch, olefins, synthesis gas, cobalt catalyst
HYDROGENATION OF CO OVER A COBALT/CERIUM OXIDE
CATALYST FOR PRODUCTION OF LOWER OLEFINS
M. HAGHSHENAS FARD1*, L. MALEKI2, M. KHOSHNOODI2
1. Department of Chemical Engineering, Islamic Azad University, Shahreza Branch, Iran
2. Department of Chemical Engineering, University of Sistan Baluchestan, Zahedan, Iran
Abstract
A cobalt/ceria catalyst has been found to be receptive for production of lower olefins from synthesis gas by Fischer Tropsch synthesis, and shows high activity for bodouard reaction. The catalyst prepared in various ageing times (the time that precipitated remains in contact with the precipitating medium) resulted in a change in CO conversion and olefin selectivity. Catalysts were prepared in a 0 and 165 minute ageing time. These catalysts were tested at various temperatures and pressures in a stainless steel micro reactor. It was found that a catalyst with 165 minute ageing time was highly receptive to ethylene and methane.
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Presented Wednesday 19, 13:30 to 15:00, in session Catalysis (T2-13P).