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European Congress of Chemical Engineering - 6
Copenhagen 16-21 September 2007

Abstract 2831 - Cure reaction and heat transfer in the cylindrical mould

Cure reaction and heat transfer in the cylindrical mould

Advancing the chemical engineering fundamentals

Chemical Reaction Engineering (T2-2P)

Dr Vanja Kosar
Faculty of Chemical Engineering and Technology
Department of Reaction Engineering and Catalysis
Savska c. 16
10000 Zagreb
Croatia
Croatia

Prof Zoran Gomzi
Faculty of Chemical Engineering and Technology
Department of Reaction Engineering and Catalysis
Savska c. 16
10000 Zagreb
Croatia
Croatia

Keywords: Curing, Polyester resin, Heat transfer coefficient, Mould, Mathematical model

The cure of unsaturated polyester was studied by using an experiment and a mathematical model of the process. The temperature-time profiles were recorded in the centre of the cylindrical mould filled with resin, also near the outer surface of the mould wall, and in the bulk of the air heated thermostat.
A numerical model was developed by taking into account heat transferred by convection from the air to the mould surface and the heat transferred by conduction through the resin, as well as the heat generated by cure reaction. Introduction of the carbon base filler reduced the amount of heat generated in the composite. As a result, it lowered the temperature of the resin. The convection heat transfer coefficient was determined from independent experiments with glycerol inside the mould.
Recording the temperature-time and conversion-time profiles developed within the sample, more extensive knowledge of the process can be obtained. The effects of the convection heat transfer to the mould, and the conduction heat transfer through the mould as well as the internal heat generated by the cure reaction is clearly shown, despite the complexity of the process.

Presented Tuesday 18, 13:30 to 15:00, in session Chemical Reaction Engineering (T2-2P).

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