Environmental Division (See also Topical 1) | |||
Session 502 - Green Processing and Applications Using Ionic Liquids | |||
The chemical industry is under considerable pressure to replace many existing processes by new technology with preferably zero or at least much less generation of chemical waste and impact on the environment as well. In particular, this holds for the fine chemical and pharmaceutical industries, which by definition generate per kg net product the highest amount of chemical waste. The occurrence of excessive amounts of chemical waste is mainly caused by insufficient atom-efficiency of the reactions performed, while the use of volatile organic solvents (VOS), both as reaction media and as product extraction solvents, are released in too large amounts into the environment. In other words, current processes quite often are not green at all. It is foreseen that ionic liquids may play an important role in designing much more green processes. This session solicits for a wide variety of contributions that considers the development of much greener processes with ionic liquids involved. | |||
Chair: | Tapas K. Das | ||
CoChair: | Cor J. Peters | ||
502a | Arene Carbonylation in Chlorometallate, Dialkylimidazolium Ionic Liquids: Effect of Changing Metal Chloride Mark G. White, Ernesto J. Angueira | ||
502b | Enzyme Structure, Function, and Utility in Room Temperature Ionic Liquids Bilge Eker, Prashanth Asuri, Saravanababu Murugesan, Robert J. Linhardt, Jonathan S. Dordick | ||
502c | Designing Green Processes: Phase Behaviour of Ionic Liquid - Carbon Dioxide Based Systems Eliane Kühne, Cor J. Peters, Geert-Jan Witkamp | ||
502d | Using Carbon Dioxide as an Antisolvent Separation Aid with Ionic Liquids: Thermodynamics and Solvent Strength Berlyn R. Mellein, Joan F. Brennecke | ||
502e | Decomposition of Ionic Liquids in Chemical Processing Maaike C. Kroon, Wim Buijs, Cor J. Peters, Geert-Jan Witkamp | ||
502f | Hydrogen Bonds in Imidazolium-Based Ionic Liquids with –Nh2: Ab Initio and Molecular Dynamics Study Guangren Yu, Suojiang Zhang | ||
502g | Measurement of the Selective Solubilities of Ch4/C2H6/Co2-Mixtures on Alkylsulphate Ionic Liquids for Natural- and Biogas Cleaning Thilo Weibert, Andreas Harndt, Marcus Petermann, Hans W. Lösch, Frieder Dreisbach | ||
502h | Grafted Poly(Ionic Liquid) Membranes for Co2 Separation Xudong Hu, Jianbin Tang, Youqing Shen, Maciej Radosz | ||
502i | Solubilities and Mass Transfer Coefficients of Gaseous Mixtures in Physical Solvents for Co2 Capture Applications Yannick J. Heintz, Laurent Sehabiague, Badie I. Morsi, Kenneth L. Jones, Henry W. Pennline |
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