To get the best CVs, run the CV_MGR.m with UniSim steady-state file (CV_MGR). The other UniSim files (no.4_temp_control, no.20_temp_control, CO2_comp_control are in dynamic mode for comparison of loss in presence of disturbances. ModDev.1 is a PDS file, which gives the identified model for design MPC. MPC-Loop_disturbances.usc is the results of MPC control. To run the file .xs and .xm files are needed to load in UniSim RMPCT. Large_fluegas_feedrate.usc shows that proposed structure fails, when reboiler duty saturates. reconfigured-large-fluegas.usc shows stability of the structure against large feedrates.