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(Invited plenary lecture). Preprints IFAC-symposium DYCORD+'92, 1-25, Maryland, Apr. 27-29, 1992 (Reprinted in 1997 in MIC).
Abstract.
Distillation column dynamics and control has been viewed by many as a very
mature or even dead field. However, as is discussed in this paper significant
new results have appeared over the last 5-10 years. These results include
multiple steady states and instability in simple columns with ideal
thermodynamics (which was believed to be impossible), the understanding of the
difference between various control configurations and the systematic
transformation between these, the feasibility of using the distillate-bottom
structure for control (which was believed to be impossible), the importance of
flow dynamics for control studies, the fundamental problems in identifying
models from open-loops responses, the use of simple regression estimators to
estimate composition from temperatures, and an improved general understanding
of the dynamic behavior of distillation columns which includes a better
understanding of the fundamental difference between internal and external
flow, simple formulas for estimating the dominant time constant, and a
derivation of the linearizing effect of logarithmic transformations. These
issues apply to all columns, even for ideal mixtures and simple columns with
only two products. In addition, there have been significant advances for cases
with complex thermodynamics and complex column configurations. These include
the behavior and control of azeotropic distillation columns, and the possible
complex dynamics of nonideal mixtures and of interlinked columns. However,
both for the simple and more complex cases there are still a number of areas
where further research is needed.