449d Non-Lithographic Microetching of Transparent Conductive Oxides (Ito and Zno) and Semiconductors (Gaas) Based on Reaction-Diffusion

Stoyan K. Smoukov and Bartosz A. Grzybowski. Chemical & Biological Engineering, Northwestern University, 2145 Sheridan Rd/TECH E136, Evanston, IL 60208

A benchtop, one-step, maskless-but-parallel method of etching micropatterns is described. Transparent conducting oxides and semiconductors are etched with lateral resolution down to 200nm using a reaction-diffusion process. Patterned hydrogel stamps act as a reservoir and a two-way "pump" transporting etchant onto the substrate while removing reaction products into its bulk. This low-cost method is suitable for rapid rototyping of bulk and thin film materials, minimizing the need for multistep lithographic processing.