372a Modeling and Process Design of an Internally Heat-Integrated Distillation Column

Keigo Matsuda1, Koichi Iwakabe2, Masaru Nakaiwa3, Toshinari Nakanishi4, Takao Ohmori5, Akira Endo5, Takuji Yamamoto5, and Sho Kataoka5. (1) Research Institute for Innovation in Sustainable Chemistry, National Institute of Advanced Industrial Science and Technology, Central 5, 1-1-1, Higashi, Tsukuba, 305-8565, Japan, (2) Project Development Department, Maruzen Petrochemical Co., Ltd., Energy-Efficient Chemical Systems Group, Research Institute for Innovation in Sustainable Chemistry, AIST Tsukuba Central 5, 1-1-1, Higashi, Tsukuba-shi, Ibaraki, 305-8565, Japan, (3) Energy-Efficient Chemical Systems Group, Research Institute for Innovation in Sustainable Chemistry, National Institute of Advanced Industrial Science and Technology, Tsukuba Central 5, 1-1-1, Higashi, Tsukuba-shi, Ibaraki, 305-8565, Japan, (4) Kimura Chemical Plants Co. Ltd., 2-1-2, Terajima Kuise, Amagasaki,, Hyogo, 660-8567, Japan, (5) Research Institute for Innovation in Sustainable Chemistry, National Institute of Advanced Industrial Science and Technology (AIST), Higashi 1-1-1, Tsukuba, Japan

The proposed of the present work is to develop a modeling and process design of the HIDiC. The model of HIDiC with structured packing is developed by rate-based model using Maxwell-Stefan equations. In this study, we have developed the HIDiC models by the process simulator “gPROMS”. Comparison of observed data from bench-scale (benzene-toluene system) separation concentric HIDiC plant, in which consisted of about 20 m in height and 254 mm in diameter. Predicted simulation results show a good agreement with observed data. The bench HIDiC showed about 40 % reduction of energy consumption than the conventional distillation column. The effect of process design in the HIDiC is also discussed.