299ab Hydrogen Production from Natural Gas Reforming in Gliding Arc Discharge

Nongnuch Rueangjitt, Chalermrat Akarawitoo, and Chavadej Sumaeth. The Petroleum and Petrochemical College, Chulalongkorn University, Soi Chula 12, Phyathai Rd., Pathumwan, 10330, Bangkok, Thailand

Natural gas resources with high concentrations of carbon dioxide have been found in several areas, including Thailand. The reforming of carbon dioxide with methane should be a promising way to directly utilize the natural gas without any prior separation process, resulting in it being more economical in terms of cutting down the high cost of an additional separation unit and reducing the net emission of carbon dioxide as a greenhouse gas. The objective of the present work was to investigate the reforming of simulated natural gas via the nonthermal plasma process with the focus on hydrogen production. The reforming of simulated natural gas was conducted in an alternating current (AC) gliding arc reactor under ambient conditions. The feed composition of the simulated natural gas contained a CH4/C2H6/C3H8/CO2 molar ratio of 70/5/5/20. To investigate the effects of all gaseous hydrocarbons and CO2 in the natural gas, the plasma reactor was operated with different feed compositions: pure CH4, CH4/He, CH4/C2H6/He, CH4/C2H6/C3H8/He, and CH4/C2H6/C3H8/CO2. In comparisons among all the studied systems, hydrogen selectivity was found to depend on the feed composition in the following order: CH4/C2H6/C3H8/CO2 > CH4/C2H6/C3H8/He > pure CH4 > CH4/C2H6/He > CH4/He. The maximum hydrogen concentration, about 6 mol%, was found in the CH4/C2H6/C3H8/CO2 system. In terms of energy consumption for converting all reactant molecules, the CH4/C2H6/C3H8/CO2 system required the lowest input energy in the range of 15 to 25 eV/molecule of reactants converted. For the simulated natural gas, the conversions of CH4, C2H6, C3H8 and CO2 increased with increasing applied voltage, but the CO and C4H10 selectivities decreased. An increase in frequency resulted in lowering the conversions of all reactants and the selectivities of H2 and C2H2, whereas the selectivities of C2H4, C4H10 and CO tended to increase.