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Azeotropic phase equilibrium diagrams: a survey
V. N. Kiva, E. K. Hilmen and S. Skogestad

Chemical Engineering Science
58 (10), pp 1903-1953, 2003

Abstract

An analysis of the structural properties of vapor-liquid equilibrium (VLE) diagrams provides a fundamental understanding of the thermodynamic behavior of azeotropic mixtures upon distillation.

In addition to a review of well-known fundamental work on the analysis of VLE diagrams, this survey comprises less known published results, especially from the Russian literature. Some new results are also presented for the first time.