-------------------------------------------------------------------- The Extension of the Attainable Region Approach for Synthesizing Reactors to Allow for Choice of Control Policies -------------------------------------------------------------------- S. Godorr, C. McGregor, D. Hildebrandt and D. Glasser School of Process and Materials Engineering, University of the Witwatersrand. P.Bag 3, WITS 2050, South Africa E-Mail Address: dihil@chemeng.chmt.ac.za Tel No: 11- 716 2413 Fax No: 11- 339 7213 Abstract: Previously the Attainable Region (AR) has been found for systems where the rate vector is uniquely defined by the characteristic vector. We now examine problems where there is also a free parameter, such as temperature or a reactant concentration, which also needs to be chosen at each point. This means that the rate vector is no longer uniquely defined by the characteristic vector, but can take on a range of values for each value of the characteristic vector. We derive a set of conditions that need be satisfied in order that rate vectors do not point outwards on the boundary of the AR. We use these conditions to solve a number of examples. In the examples in which mixing does not occur in the boundary of the AR, we have shown that the results agree with those derived from Pontryagins Maximum Principle. In more general cases we have been able to simultaneously generate the optimal reactor structures with their associated optimal control policies.